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Class 12 Chemistry · Chapter 2 · Physical Chemistry 🔴 Hard

Electrochemistry

From the battery in your phone to the rust on an old gate — the chemistry of electrons moving through circuits and ions moving through solutions. With interactive Nernst calculator, Faraday's laws calculator, animated cell diagrams, and 20+ real-life examples.

⏱️ ~40 min read · 📚 9 sections · 🧮 3 calculators · 🎯 7 solved + 10 NCERT
9Sections
20+Real-life Examples
10Diagrams & Tables
3Calculators
18MCQs
The Big Picture

🗺️ How Everything Connects

Before diving in, here's the entire chapter on one page. This is your mental map — how cells, EMF, Nernst equation, conductance, and electrolysis all connect.

Galvanic Cells Standard Potential Nernst Equation ΔG & Equilibrium Conductance + Kohlrausch Electrolysis Faraday Applications Batteries "How does chemistry produce electricity, and vice versa?" Galvanic cells: chemistry → electricity. Electrolysis: electricity → chemistry
Key Takeaway

Electrochemistry studies the interconversion of chemical and electrical energy. Galvanic cells (spontaneous) generate EMF; electrolytic cells (non-spontaneous) consume electricity. Nernst equation links EMF to concentration. Conductance and Kohlrausch's law describe ion mobility. Faraday's laws quantify electrolysis. Applications: batteries, corrosion prevention, electroplating, fuel cells.

Section 01

Electrochemical (Galvanic) Cells

2.1Chemistry → Electricity

Electrochemical Cell

Electrochemical cell: A device that converts chemical energy of a redox reaction into electrical energy (galvanic cell) or vice versa (electrolytic cell).

Galvanic (Voltaic) cell: Produces electricity from a spontaneous redox reaction.

Electrolytic cell: Uses electricity to drive a non-spontaneous reaction.

In both cases, oxidation happens at anode and reduction happens at cathode.

Daniell Cell — The Classic Example

Zn(s) | Zn²⁺(aq) || Cu²⁺(aq) | Cu(s)

  • Anode: Zn electrode in ZnSO₄ solution. Zn → Zn²⁺ + 2e⁻ (oxidation)
  • Cathode: Cu electrode in CuSO₄ solution. Cu²⁺ + 2e⁻ → Cu (reduction)
  • Overall: Zn + Cu²⁺ → Zn²⁺ + Cu
  • EMF: ≈ 1.1 V under standard conditions

Electrons flow from Zn to Cu through external circuit.

Salt bridge (KCl): Connects the two solutions. Allows ion flow (K⁺ to cathode, Cl⁻ to anode) to maintain electrical neutrality. Prevents mixing of solutions.

V1 · Daniell cell — Zn-Cu galvanic cell ZnSO₄ solution Zn ANODE (−) CuSO₄ solution Cu CATHODE (+) Salt bridge (KCl) V e⁻ flow → Zn → Zn²⁺ + 2e⁻ Cu²⁺ + 2e⁻ → Cu Zn²⁺ Zn²⁺ Cu²⁺ Cu²⁺ Overall Reaction: Zn + Cu²⁺ → Zn²⁺ + Cu E°_cell ≈ 1.10 V
Cell Notation (IUPAC Convention)

Anode | Anode solution || Cathode solution | Cathode

Single vertical line | = phase boundary

Double vertical line || = salt bridge

For Daniell cell: Zn(s) | Zn²⁺(aq) || Cu²⁺(aq) | Cu(s)

Left = anode (oxidation), right = cathode (reduction)

Standard Electrode Potential (E°)

Standard electrode potential: The potential difference between an electrode and the Standard Hydrogen Electrode (SHE) when the concentration of ions is 1 M, pressure is 1 bar, at 298 K.

SHE: Pt | H₂ (1 bar) | H⁺ (1 M). Assigned E° = 0.00 V by convention.

Half-cell with reference: E°_cell = E°_cathode − E°_anode

For Daniell cell: E°_cell = E°(Cu²⁺/Cu) − E°(Zn²⁺/Zn) = 0.34 − (−0.76) = 1.10 V

V2 · Electrochemical series — standard reduction potentials Standard Reduction Potentials (E°, volts) −3.0 −2.0 −1.0 0 +1.0 +2.0 +3.0 SHE (0 V) Li⁺/Li −3.04 K⁺/K −2.92 Na⁺/Na −2.71 Zn²⁺/Zn −0.76 Fe²⁺/Fe −0.44 H⁺/H₂ 0.00 Cu²⁺/Cu +0.34 Ag⁺/Ag +0.80 Au³⁺/Au +1.50 Strong reducing agents Strong oxidizing agents Lower E° = more readily oxidized Higher E° = more readily reduced
Key Rules from Electrochemical Series
  • More negative E° → stronger reducing agent → more easily oxidized → used as anode
  • More positive E° → stronger oxidizing agent → more easily reduced → used as cathode
  • A metal with higher E° can displace a metal with lower E° from its solution
  • Example: Zn (E° = −0.76 V) displaces Cu (E° = +0.34 V) from CuSO₄
  • Metals above H (E° < 0) can displace H₂ from acids
Real Life Connect
  • Battery in your phone: Li-ion battery operates on similar principles (LiCoO₂ cathode, graphite anode)
  • Car battery: Lead-acid accumulator (Pb/PbO₂ in H₂SO₄)
  • Coin cell: Silver-zinc, mercury, or Li-MnO₂ cells
  • Fuel cells in spacecraft: H₂-O₂ fuel cell produces electricity + water
  • Electroplating gold jewelry: Electrolytic cell with Au at anode, jewelry at cathode
  • pH meters: Glass electrode + calomel reference — galvanic cell
Key Takeaway

Galvanic cell = spontaneous redox → electricity. Anode = oxidation (Zn), cathode = reduction (Cu). Cell notation: anode | solution || solution | cathode. E°_cell = E°_cathode − E°_anode. Electrochemical series ranks elements by reducing/oxidizing power.

Section 02

Nernst Equation

2.2EMF vs Concentration

The standard cell potential E°_cell applies at 1 M concentration. For real cells, concentration affects EMF. The Nernst equation quantifies this.

Nernst Equation

For a general cell reaction: aA + bB → cC + dD

E_cell = E°_cell − (RT/nF) ln Q

Where Q = [C]^c [D]^d / [A]^a [B]^b (reaction quotient)

At 298 K (25°C), using base-10 log:

E_cell = E°_cell − (0.0591/n) log Q

Where n = number of electrons transferred in the balanced equation.

For Daniell Cell

Reaction: Zn + Cu²⁺ → Zn²⁺ + Cu (n = 2)

Q = [Zn²⁺] / [Cu²⁺]

E_cell = E°_cell − (0.0591/2) log([Zn²⁺]/[Cu²⁺])

E°_cell = 1.10 V

  • If [Zn²⁺] increases → Q increases → log Q increases → E decreases
  • If [Cu²⁺] increases → Q decreases → E increases
  • At equilibrium (E = 0): log Q = log K → K = 2nE°_cell/0.0591

Nernst Equation Calculator

Enter concentrations and temperature — calculate actual cell potential.

Reaction Quotient Q
—
E_cell (V)
—
Nernst Equation — Applications
  • Concentration cells: Two electrodes of same metal, different ion concentrations → small EMF
  • pH measurement: Glass electrode + reference → pH from voltage
  • Solubility product: Concentration cell with sparingly soluble salt → K_sp
  • Equilibrium constant: E°_cell = (0.0591/n) log K
  • Biological membranes: Nerve impulse is essentially a Nernst-type potential
Analogy — Nernst Equation

Think of a river flowing downhill. E°_cell is the "standard drop." If the "bottom" (product side) is crowded (high concentration), it's harder for water to flow → smaller drop. If "bottom" is empty (low product concentration), flow is easier → larger drop. Nernst equation tells you how the "crowding" affects the flow (voltage).

Real Life Connect
  • Concentration cells in nature: Nerve impulse = Na⁺/K⁺ concentration difference across membrane → ~70 mV potential
  • pH meter: Measures EMF of glass electrode vs reference — uses Nernst equation
  • Battery losing power: As products accumulate and reactants deplete, E drops (Nernst equation)
  • Fuel cell performance: Cell voltage decreases with usage due to concentration changes
Common Mistake

Mistake: "0.0591 is always divided by 2."
Correction: 0.0591 is divided by n, the number of electrons transferred in the specific reaction. For Li-ion battery, n = 1 (per Li⁺). For Al³⁺/Al, n = 3. Always check the balanced equation!

Key Takeaway

Nernst: E = E° − (0.0591/n) log Q at 298 K. Q = products/reactants. Higher product concentration → lower E. At equilibrium E = 0, so K relates to E°_cell. Essential for concentration cells, pH meters, and understanding real battery behaviour.

Section 03

Gibbs Energy and EMF

2.3Thermodynamics Meets Electrochemistry

Key Relationships

ΔG = −nFE

ΔG° = −nFE°_cell

Where:

  • ΔG = Gibbs free energy change (J)
  • n = number of electrons transferred
  • F = Faraday's constant = 96,485 C/mol
  • E = cell potential (V)

ΔG° = −RT ln K

Combining: −nFE°_cell = −RT ln K → E°_cell = (RT/nF) ln K

At 298 K: E°_cell = (0.0591/n) log K

Interpretation
ΔG E_cell K Meaning
ΔG < 0 E > 0 K > 1 Spontaneous — galvanic cell works
ΔG = 0 E = 0 K = 1 At equilibrium — dead battery
ΔG > 0 E < 0 K < 1 Non-spontaneous — needs external voltage
Work Done by the Cell

Maximum electrical work = −ΔG (at constant T, P)

W_max = nFE_cell (joules)

For Daniell cell with 1 mol Zn reacting: W = 2 × 96485 × 1.10 = 2.12 × 10⁵ J/mol ≈ 212 kJ/mol

Faraday's constant: F = N_A × e = 6.022×10²³ × 1.602×10⁻¹⁹ = 96,485 C/mol

Real Life Connect
  • Battery capacity: Higher E°_cell → more work per electron → longer battery life (other factors being equal)
  • Fuel cell efficiency: ΔG determines theoretical max efficiency (H₂-O₂ ~83%)
  • Electrolysis cost: Non-spontaneous reaction needs external voltage > E°_cell to overcome ΔG
  • Photosynthesis: Uses light energy to drive thermodynamically uphill reactions (ΔG > 0)
Key Takeaway

ΔG = −nFE. Spontaneous redox → ΔG < 0 → E > 0. At equilibrium, E = 0, K from E°_cell = (0.0591/n) log K. Maximum work = nFE. Links thermodynamics to electrochemistry.

Section 04

Conductance of Electrolytic Solutions

2.4How Well Do Ions Conduct?

Basic Definitions

Resistance (R): Opposition to flow of current. Units: Ω (ohm)

Conductance (G): Reciprocal of resistance. G = 1/R. Units: S (siemens) or Ω⁻¹

Resistivity (ρ): R = ρ l/A. Units: Ω·cm

Conductivity (κ): κ = 1/ρ = G · (l/A). Units: S/cm

Cell constant: l/A (cm⁻¹)

Molar conductivity (Λ_m): Conducting power of 1 mole of electrolyte in solution

Λ_m = κ × 1000 / M

Where κ in S/cm, M in mol/L → Λ_m in S·cm²/mol

Factors Affecting Conductivity
  • Nature of electrolyte: Strong electrolytes (NaCl, HCl) fully dissociate → high κ. Weak electrolytes (CH₃COOH) partially dissociate → low κ
  • Concentration: κ increases with concentration (more ions), but Λ_m decreases (ions crowd each other)
  • Temperature: κ increases with T (higher mobility)
  • Nature of solvent: Low viscosity, high dielectric constant solvents → higher κ
V3 · Molar conductivity vs √c for strong and weak electrolytes Λ_m vs √c — Kohlrausch's observation √c (mol/L)^½ → Λ_m (S·cm²/mol) → Strong (NaCl, HCl) linear, extrapolates to Λ°_m Λ°_m (at c → 0) Weak (CH₃COOH) curved — cannot extrapolate Kohlrausch's Law Λ_m = Λ°_m − A√c (for strong electrolytes, low c) A = constant depending on solvent, T As c → 0, Λ_m → Λ°_m (limiting molar conductivity)

Molar Conductivity Calculator

Enter conductivity and molarity — calculate molar conductivity and degree of dissociation.

Molar Conductivity Λ_m
—
Degree of Dissociation α
—
Kohlrausch's Law of Independent Migration

At infinite dilution, the molar conductivity of an electrolyte is the sum of the contributions of its individual ions.

Λ°_m(A_xB_y) = x·λ°(A^y+) + y·λ°(B^x−)

Where λ° is the limiting molar conductivity of each ion.

Example: Λ°_m(NaCl) = λ°(Na⁺) + λ°(Cl⁻) = 50.1 + 76.3 = 126.4 S·cm²/mol

Applications of Kohlrausch's Law
  • Calculate Λ°_m of weak electrolytes: Can't extrapolate from curve, but can add ion contributions from strong electrolytes
  • Calculate degree of dissociation: α = Λ_m / Λ°_m
  • Calculate dissociation constant: K_a = Cα²/(1−α)
  • Calculate solubility of sparingly soluble salts: κ of saturated solution / Λ°_m

Example: Λ°_m(CH₃COOH) = Λ°_m(CH₃COONa) + Λ°_m(HCl) − Λ°_m(NaCl)

Real Life Connect
  • TDS meters (water quality): Measure conductivity of water → estimate dissolved salts
  • Battery acid (H₂SO₄): High conductivity — measures state of charge
  • Electroplating baths: High conductivity salts (NaCN, H₂SO₄) added to improve plating
  • Deionized water: Very low κ (~0.055 μS/cm) — no dissolved ions
  • Sea water: Very high κ (~5 S/m) — NaCl + other salts
  • Fuel cells: KOH or Nafion membranes selected for conductivity
Key Takeaway

Conductivity κ = G(l/A). Molar conductivity Λ_m = 1000κ/M. For strong electrolytes, Λ_m vs √c is linear (Kohlrausch). Λ°_m = sum of ion contributions. Applications: degree of dissociation, K_a, solubility of salts, TDS meters.

Section 05

Kohlrausch's Law — Deep Dive

2.5Independence of Ions

Statement and Meaning

Kohlrausch's Law: At infinite dilution, each ion makes a definite contribution to the total molar conductivity of an electrolyte, independent of the nature of the other ion.

Λ°_m = ν_+ λ°_+ + ν_− λ°_−

Where ν_+ and ν_− are numbers of cations and anions per formula unit.

Useful Applications

1. Λ°_m of weak electrolyte

Λ°_m(CH₃COOH) = Λ°_m(CH₃COONa) + Λ°_m(HCl) − Λ°_m(NaCl)

because: CH₃COO⁻ + Na⁺ + H⁺ + Cl⁻ − Na⁺ − Cl⁻ = CH₃COO⁻ + H⁺

2. Degree of dissociation (α)

α = Λ_m / Λ°_m

For weak electrolyte (partial dissociation), α tells fraction dissociated.

3. Dissociation constant (K_a)

K_a = C·α² / (1 − α)

For dilute weak electrolyte (α << 1): K_a ≈ C·α²

4. Solubility of sparingly soluble salts

s = κ(saturated solution) × 1000 / Λ°_m

Where s is solubility in mol/L.

Why Can't We Measure Λ°_m of Weak Electrolytes Directly?

Weak electrolytes have very low Λ_m even at moderate concentrations, and their Λ_m vs √c curve is very steep at low concentrations. It never becomes linear, so no extrapolation to c=0 is possible. That's why Kohlrausch's law is essential — we build Λ°_m from strong electrolyte data.

Key Takeaway

Kohlrausch's law: Λ°_m = sum of independent ion contributions. Enables calculation of Λ°_m for weak electrolytes, degree of dissociation α = Λ_m/Λ°_m, K_a = Cα²/(1−α), and solubility of sparingly soluble salts.

Section 06

Electrolysis and Faraday's Laws

2.6Electricity → Chemistry

Electrolytic Cell vs Galvanic Cell
Feature Galvanic Cell Electrolytic Cell
Energy conversion Chemical → Electrical Electrical → Chemical
Reaction Spontaneous (ΔG < 0) Non-spontaneous (ΔG > 0)
Anode Negative (−) Positive (+)
Cathode Positive (+) Negative (−)
Electron flow Anode → Cathode (external) Anode → Cathode (external)
Example Daniell cell Electrolysis of water
Faraday's First Law of Electrolysis

The mass of substance deposited or liberated at an electrode is directly proportional to the quantity of electricity passed.

m = Z·I·t

Where:

  • m = mass deposited (g)
  • Z = electrochemical equivalent (g/C) = M/(nF)
  • I = current (A)
  • t = time (s)
  • M = molar mass, n = electrons per ion
  • F = 96,485 C/mol

Also: m = (M·I·t)/(n·F) = (M·Q)/(n·F)

Faraday's Second Law of Electrolysis

When the same quantity of electricity is passed through different electrolytes, the masses deposited are proportional to their equivalent weights.

m₁/m₂ = (M₁/n₁) / (M₂/n₂)

Where M₁/n₁ and M₂/n₂ are equivalent masses.

1 Faraday (1 F)

1 Faraday = 96,485 C/mol = charge on 1 mole of electrons

Charge on 1 electron = 1.602 × 10⁻¹⁹ C

1 F = N_A × e = 6.022×10²³ × 1.602×10⁻¹⁹ = 96,485 C/mol

So passing 1 F of charge deposits 1 mole of monovalent ions (like Ag⁺ → Ag), 0.5 mol of divalent ions (like Cu²⁺ → Cu), etc.

Faraday's Laws Calculator

Enter current, time, and ion details — calculate mass deposited.

Charge Q (C)
—
Mass Deposited (g)
—
Products of Electrolysis

Electrolysis of molten NaCl:

  • Anode: 2Cl⁻ → Cl₂ + 2e⁻ (chlorine gas)
  • Cathode: Na⁺ + e⁻ → Na (sodium metal)
  • Product: Na metal + Cl₂ gas (used in Down's process)

Electrolysis of aqueous NaCl (brine):

  • Anode: 2Cl⁻ → Cl₂ + 2e⁻ (Cl₂ gas)
  • Cathode: 2H₂O + 2e⁻ → H₂ + 2OH⁻ (hydrogen gas + NaOH formed)
  • Product: Cl₂ + H₂ + NaOH (chlor-alkali process)

Electrolysis of water (acidified):

  • Anode: 2H₂O → O₂ + 4H⁺ + 4e⁻
  • Cathode: 4H⁺ + 4e⁻ → 2H₂
  • Overall: 2H₂O → 2H₂ + O₂ (volume ratio 2:1)
Real Life Connect
  • Aluminium extraction: Hall-Héroult process — electrolysis of Al₂O₃ in cryolite. ~20,000 A current. Uses ~15 kWh/kg Al
  • Chlor-alkali industry: Electrolysis of brine → Cl₂, H₂, NaOH (billions of kg/year)
  • Electroplating: Jewelry, silverware, chrome on cars, tin cans — all use electrolysis
  • Electrorefining of copper: 99.99% pure Cu for electrical wiring
  • Electrolysis of water: Produces H₂ for fuel cells (green hydrogen)
  • Lithium extraction: Li from LiCl-KCl molten salt (for Li-ion batteries)
  • Anodizing aluminium: Electrolytic oxidation of Al surface for corrosion resistance
Key Takeaway

Electrolysis uses electricity to drive non-spontaneous reactions. Faraday's 1st law: m = MIt/nF. 2nd law: masses ∝ equivalent weights. 1 F = 96,485 C = 1 mol electrons. Applications: metal extraction (Al), chlor-alkali, electroplating, H₂ production.

Section 07

Batteries

2.7Portable Power

Types of Batteries

Primary batteries: Cannot be recharged. Reaction is irreversible.

Secondary batteries: Can be recharged. Reaction is reversible.

Fuel cells: Continuously fed with fuel; produce electricity as long as fuel is supplied.

Primary Batteries

1. Dry cell (Leclanché cell):

  • Anode: Zn (zinc can)
  • Cathode: MnO₂ + carbon (graphite rod)
  • Electrolyte: paste of NH₄Cl + ZnCl₂ (moist)
  • Anode: Zn → Zn²⁺ + 2e⁻
  • Cathode: 2MnO₂ + 2H₂O + 2e⁻ → 2MnO(OH) + 2OH⁻
  • EMF: 1.5 V. Used in flashlights, toys, remotes.
  • Why it dies: Zn is consumed, internal resistance increases.

2. Mercury cell:

  • Anode: Zn-Hg amalgam
  • Cathode: HgO (mercury(II) oxide)
  • Electrolyte: KOH + ZnO paste
  • Voltage: ~1.35 V — constant during life (unlike dry cell)
  • Used in watches, hearing aids, pacemakers
  • Environmental concern: mercury toxicity
Secondary Batteries

1. Lead-acid battery (car battery):

  • Anode: Pb (lead)
  • Cathode: PbO₂ (lead dioxide) on lead grid
  • Electrolyte: 38% H₂SO₄ (concentrated sulfuric acid)
  • Discharge reactions:
    • Anode: Pb + SO₄²⁻ → PbSO₄ + 2e⁻
    • Cathode: PbO₂ + 4H⁺ + SO₄²⁻ + 2e⁻ → PbSO₄ + 2H₂O
  • Overall: Pb + PbO₂ + 2H₂SO₄ → 2PbSO₄ + 2H₂O
  • EMF: 2 V per cell → 12 V with 6 cells in series
  • Rechargeable — reversible reaction

2. Nickel-Cadmium (Ni-Cd) battery:

  • Anode: Cd, Cathode: NiO(OH)
  • Electrolyte: KOH
  • EMF: 1.2 V
  • Memory effect — must be fully discharged before recharging
  • Environmental concern: cadmium toxicity

3. Lithium-ion battery (modern):

  • Anode: Graphite (Li intercalated)
  • Cathode: LiCoO₂ / LiFePO₄
  • Electrolyte: LiPF₆ in organic solvent
  • EMF: 3.7 V per cell
  • High energy density, no memory effect, low self-discharge
  • Powers phones, laptops, electric vehicles
Fuel Cells

H₂-O₂ fuel cell (Bacon cell):

  • Anode: Porous carbon + Pt/Pd catalyst
  • Cathode: Porous carbon + Pt/Pd catalyst
  • Electrolyte: Concentrated KOH or NaOH
  • Anode: 2H₂ + 4OH⁻ → 4H₂O + 4e⁻
  • Cathode: O₂ + 2H₂O + 4e⁻ → 4OH⁻
  • Overall: 2H₂ + O₂ → 2H₂O
  • Efficiency: ~70% (vs 30-40% for combustion engines)
  • Used in spacecraft (Apollo, Gemini, Space Shuttle) — produces drinking water as byproduct
  • Zero pollution — only water as byproduct

Other fuel cells: Methanol fuel cells (DMFC), solid oxide fuel cells (SOFC), phosphoric acid fuel cells (PAFC).

Battery EMF/cell Rechargeable? Application
Dry cell (Leclanché) 1.5 V No Flashlights, toys
Mercury cell 1.35 V No Watches, pacemakers
Lead-acid 2.0 V Yes Cars, UPS, inverters
Ni-Cd 1.2 V Yes Power tools (older)
Li-ion 3.7 V Yes Phones, EVs, laptops
H₂-O₂ fuel cell ~1.2 V (loaded) Continuous Spacecraft, prototypes
Real Life Connect
  • Car battery: 12 V lead-acid — starts engine (~200-600 A for 2-3 s)
  • Phone battery: Li-ion ~3.7 V — 4000 mAh typical capacity
  • Tesla Model 3: ~80 kWh Li-ion pack, ~350 V
  • Toyota Mirai: H₂ fuel cell EV — 5 min refuel, 650 km range
  • Mars rovers: Li-ion + solar (Curiosity, Perseverance)
  • International Space Station: H₂-O₂ fuel cells + solar
  • Pacemakers: Li-iodine cells — last 8-10 years
Did You Know?

The H₂-O₂ fuel cell was invented by William Grove in 1839, but it took 130 years to be practical. NASA used it in the Apollo missions — the fuel cells provided electricity AND drinking water for astronauts!

Key Takeaway

Batteries: primary (irreversible — dry cell, mercury) vs secondary (reversible — lead-acid, Ni-Cd, Li-ion) vs fuel cells (continuous fuel supply — H₂-O₂). Lead-acid: 2 V/cell. Li-ion: 3.7 V/cell, best energy density. Fuel cells: clean, high efficiency.

Section 08

Corrosion

2.8When Metals Fall Apart

Corrosion

Corrosion: Gradual deterioration of metals due to chemical or electrochemical reaction with the environment.

Rusting of iron: The most common example. Iron is oxidized to hydrated iron(III) oxide (rust).

Electrochemical mechanism of rusting:

  • At anode (small area of iron): Fe → Fe²⁺ + 2e⁻
  • At cathode (larger area): O₂ + 4H⁺ + 4e⁻ → 2H₂O (in acidic) OR O₂ + 2H₂O + 4e⁻ → 4OH⁻ (in neutral)
  • Fe²⁺ further oxidized by air: 4Fe²⁺ + O₂ + 4H₂O → 2Fe₂O₃ + 8H⁺
  • Overall: 4Fe + 3O₂ + xH₂O → 2Fe₂O₃·xH₂O (rust)
Conditions Necessary for Rusting
  • Presence of oxygen (from air)
  • Presence of moisture (water)
  • Presence of electrolyte (salt accelerates rusting)

That's why iron rusts faster near the sea (salt spray) and in humid climates.

Corrosion Prevention Methods

1. Galvanization: Coating iron with zinc. Zn has more negative E° (−0.76 V) than Fe (−0.44 V), so Zn acts as a sacrificial anode and corrodes first, protecting iron. Used in galvanized steel, dustbins, roofing sheets.

2. Cathodic protection: Connect iron to a more reactive metal (Mg, Zn, Al) — the reactive metal oxidizes instead of iron. Used for underground pipelines, ship hulls.

3. Painting / coating: Physical barrier prevents contact with O₂ and H₂O. Used for cars, gates, buildings.

4. Alloying: Stainless steel (Fe + Cr + Ni) resists rust because Cr forms a protective Cr₂O₃ layer.

5. Electroplating: Deposit a thin layer of a noble metal (Cr, Ni, Sn) on iron. Used in tin cans (tin-plated steel), chrome plating.

6. Oiling / greasing: Prevents air and moisture from reaching surface.

Why Some Metals Don't Corrode Easily
  • Gold, platinum: Very positive E° — don't oxidize under normal conditions
  • Aluminium: Reacts with air, but forms a thin adherent Al₂O₃ layer that protects further oxidation
  • Chromium: Forms protective Cr₂O₃ layer
  • Stainless steel: Cr₂O₃ layer from Cr content
Real Life Connect
  • Rusty bicycle: Iron + rain + oxygen = rust
  • Statue of Liberty: Copper skin turned green (basic copper carbonate, patina)
  • Taj Mahal: Marble yellowing due to SO₂ pollution — different mechanism, but problem
  • Ship hulls: Use zinc sacrificial anodes — one block dissolves to protect entire ship
  • Pipelines: Cathodic protection with Mg/Zn anodes
  • Silver tarnish: Ag + H₂S → Ag₂S (black)
  • Aluminium pans: Don't corrode easily — Al₂O₃ protective layer
Did You Know?

Corrosion costs the world economy an estimated $2.5 trillion per year — about 3-4% of global GDP. Rust alone damages infrastructure, transport, and machinery globally.

Key Takeaway

Corrosion = electrochemical degradation. Rusting of iron = Fe → Fe²⁺ at anode, O₂ reduction at cathode, forming Fe₂O₃·xH₂O. Prevention: galvanization (Zn sacrificial), cathodic protection (Mg/Zn anodes), painting, alloying (stainless steel), electroplating.

Memory Aids

🧠 Mnemonics & Memory Tricks

🎯 Chapter-Wide Memory Aids

Electrochemical Series — Metals Order

"Please Send Cats Monkeys And Zebras In Large Hairy Cages So Gold Prefers Costly Arguments"

K, Na, Ca, Mg, Al, Zn, Fe, Pb, H, Cu, Hg, Ag, Au

(K is most reactive, Au is least)

Anode vs Cathode

"AN OX and RED CAT"

ANode → OXidation

REDuction → CAThode

Always true — for both galvanic and electrolytic cells!

Galvanic Cell Signs

"Galvanic: Anode is negative; Electrolytic: Anode is positive"

Memory trick: In a galvanic cell, electrons flow FROM anode TO cathode externally, so anode is the source (negative terminal). In electrolysis, external power pushes electrons INTO anode, making it positive.

Nernst Equation

"0.0591 over n" at 298 K — remember 0.059 ≈ RT×ln(10)/F

At any temperature: E = E° − (2.303RT/nF) log Q

At 298 K: 2.303RT/F = 0.0591

Faraday's Laws

First law: "m = MIt/nF" — say as "M-I-t over n-F"

Second law: "Masses to equivalent weights"

1 F = 96,485 C/mol ≈ 96,500

Battery Types

"Primary is Permanent (one-way); Secondary is Switchable (rechargeable); Fuel is Fresh (continuous)"

Standard Reduction Potential Values

Zn = −0.76, Cu = +0.34, Ag = +0.80

"Zebra at −0.76, Cup +0.34, Silver +0.80"

Daniell cell E°: 0.34 − (−0.76) = 1.10 V — classic value!

Rusting Conditions

"O₂ + H₂O + Salt = Rust"

Remove any one → no rusting. That's the basis of all prevention methods.

Key Takeaway

Use "AN OX, RED CAT" for anode/cathode, "0.0591/n" for Nernst equation, "m = MIt/nF" for Faraday. Practice electrochemical series recall for E°_cell calculations.

Practice

📝 Solved Examples

📋 2 Marks

Q1. Calculate the EMF of a Zn-Cu cell at 298 K when [Zn²⁺] = 0.1 M and [Cu²⁺] = 0.01 M. E°_cell = 1.10 V.

Formula ½ Mark

E = E° − (0.0591/n) log Q, n = 2

Q ½ Mark

Q = [Zn²⁺]/[Cu²⁺] = 0.1/0.01 = 10

Calculate 1 Mark

E = 1.10 − (0.0591/2) × log(10)

E = 1.10 − 0.02955 × 1 = 1.070 V

E_cell = 1.070 V
📋 3 Marks

Q2. Calculate ΔG° for the Daniell cell. (E°_cell = 1.10 V, n = 2, F = 96485 C/mol)

Formula 1 Mark

ΔG° = −nFE°

Substitute 1 Mark

ΔG° = −2 × 96485 × 1.10

ΔG° = −212,267 J/mol ≈ −212.3 kJ/mol

Interpretation 1 Mark

Negative ΔG° → spontaneous. Maximum electrical work = 212 kJ/mol Zn.

ΔG° = −212.3 kJ/mol
📋 3 Marks

Q3. Calculate the equilibrium constant for the reaction Cu + 2Ag⁺ → Cu²⁺ + 2Ag. E°_cell = 0.46 V.

Formula 1 Mark

log K = (n × E°_cell) / 0.0591

Substitute 1 Mark

log K = (2 × 0.46) / 0.0591 = 0.92/0.0591 = 15.57

Calculate 1 Mark

K = 10^15.57 = 3.7 × 10¹⁵

Very large K → reaction goes almost to completion

K ≈ 3.7 × 10¹⁵
📋 3 Marks

Q4. Calculate the molar conductivity of a 0.1 M solution with conductivity 0.012 S/cm.

Formula 1 Mark

Λ_m = κ × 1000 / M

Substitute 1 Mark

Λ_m = 0.012 × 1000 / 0.1

Calculate 1 Mark

Λ_m = 12 / 0.1 = 120 S·cm²/mol

Λ_m = 120 S·cm²/mol
📋 5 Marks

Q5. A current of 5 A is passed through CuSO₄ solution for 30 min. Find mass of Cu deposited. (M_Cu = 63.5, n = 2)

Time in seconds 1 Mark

t = 30 × 60 = 1800 s

Charge 1 Mark

Q = I × t = 5 × 1800 = 9000 C

Moles of electrons 1 Mark

n_e = Q/F = 9000/96485 = 0.0933 mol e⁻

Moles of Cu 1 Mark

For Cu²⁺ + 2e⁻ → Cu, moles Cu = n_e/2 = 0.0466 mol

Mass of Cu 1 Mark

m = 0.0466 × 63.5 = 2.96 g

Mass Cu ≈ 2.96 g
📋 5 Marks

Q6. Λ°_m for NaCl, HCl, CH₃COONa are 126.4, 426.2, 91.0 S·cm²/mol. Calculate Λ°_m for CH₃COOH.

Kohlrausch's Law 1 Mark

Λ°_m(CH₃COOH) = λ°(CH₃COO⁻) + λ°(H⁺)

Expression using known values 1 Mark

Λ°(CH₃COOH) = Λ°(CH₃COONa) + Λ°(HCl) − Λ°(NaCl)

Verification 1 Mark

RHS: (CH₃COO⁻ + Na⁺) + (H⁺ + Cl⁻) − (Na⁺ + Cl⁻) = CH₃COO⁻ + H⁺ ✓

Calculate 1 Mark

Λ° = 91.0 + 426.2 − 126.4 = 390.8 S·cm²/mol

Significance 1 Mark

Now we can use α = Λ_m/Λ°_m for acetic acid at any concentration, then K_a = Cα²/(1−α).

Λ°_m(CH₃COOH) = 390.8 S·cm²/mol
📋 5 Marks

Q7. The conductivity of 0.001 M CH₃COOH is 4.95 × 10⁻⁵ S/cm. Λ°_m = 390.5. Find degree of dissociation and K_a.

Molar conductivity 1 Mark

Λ_m = κ × 1000 / M = 4.95×10⁻⁵ × 1000 / 0.001

Λ_m = 49.5 S·cm²/mol

Degree of dissociation 1 Mark

α = Λ_m/Λ°_m = 49.5/390.5 = 0.1268

K_a 1 Mark

K_a = Cα²/(1−α) = 0.001 × (0.1268)² / (1−0.1268)

= 0.001 × 0.01608 / 0.8732

= 1.84 × 10⁻⁵

Verify 1 Mark

Literature K_a for acetic acid = 1.8 × 10⁻⁵ ✓

Interpretation 1 Mark

Only ~12.7% of acetic acid molecules are ionized at 0.001 M — weak acid.

α ≈ 0.127, K_a ≈ 1.84 × 10⁻⁵
NCERT Textbook

📚 NCERT Exercise Questions

Selected exercise questions from NCERT Class 12 Chemistry Chapter 2. Click each to reveal the solution.

NCERT 2.1
Define the term molar conductivity. How does it change with concentration for strong and weak electrolytes?
Show Solution

Molar conductivity (Λ_m): Conducting power of 1 mole of electrolyte in solution. Λ_m = κ × 1000 / M (S·cm²/mol).

Strong electrolytes: Λ_m decreases slightly with concentration. Λ_m vs √c is linear — Kohlrausch's law: Λ_m = Λ°_m − A√c. Extrapolation to c=0 gives Λ°_m.

Weak electrolytes: Λ_m drops sharply with concentration (because fewer ions are formed at higher concentration). Cannot extrapolate to Λ°_m — must use Kohlrausch's law from strong electrolyte data.

NCERT 2.5
Calculate the standard cell potentials of galvanic cells in which the following reactions take place: (a) 2Cr(s) + 3Cd²⁺(aq) → 2Cr³⁺(aq) + 3Cd(s). Given E°(Cr³⁺/Cr) = −0.74 V, E°(Cd²⁺/Cd) = −0.40 V.
Show Solution

Solution: Cr is oxidized (anode) → 2Cr → 2Cr³⁺ + 6e⁻

Cd²⁺ is reduced (cathode) → 3Cd²⁺ + 6e⁻ → 3Cd

E°_cell = E°_cathode − E°_anode = −0.40 − (−0.74) = +0.34 V

n = 6 (per balanced equation)

ΔG° = −nFE° = −6 × 96485 × 0.34 = −196,829 J = −196.8 kJ/mol

NCERT 2.7
Why does the conductivity of a solution decrease with dilution?
Show Solution

Solution: Conductivity κ is the conductance of a unit-volume of solution. It depends on the number of ions per unit volume. When we dilute a solution, the number of ions per unit volume decreases (same total ions in more volume). Since fewer ions are available per unit length between electrodes, κ decreases.

However, molar conductivity Λ_m increases with dilution, because each mole has more "space" and can contribute fully (less ion-ion interference).

NCERT 2.9
The molar conductivity of 0.025 mol/L methanoic acid is 46.1 S·cm²/mol. Calculate the degree of dissociation and dissociation constant. Given λ°(H⁺) = 349.6, λ°(HCOO⁻) = 54.6.
Show Solution

Solution: Λ°_m(HCOOH) = 349.6 + 54.6 = 404.2 S·cm²/mol

Degree of dissociation: α = Λ_m/Λ° = 46.1/404.2 = 0.114

K_a = Cα²/(1−α) = 0.025 × (0.114)² / (1−0.114)

= 0.025 × 0.0130 / 0.886 = 3.67 × 10⁻⁴

NCERT 2.12
Consider the reaction: Cr₂O₇²⁻ + 14H⁺ + 6I⁻ → 2Cr³⁺ + 7H₂O + 3I₂. What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr₂O₇²⁻?
Show Solution

Solution: Each Cr₂O₇²⁻ accepts 6 electrons to become 2Cr³⁺.

1 mol Cr₂O₇²⁻ requires 6 mol electrons.

Q = nF = 6 × 96485 = 578,910 C ≈ 5.79 × 10⁵ C

NCERT 2.15
Calculate the potential of a hydrogen electrode in contact with a solution whose pH is 10.
Show Solution

Solution: For hydrogen electrode: H⁺ + e⁻ → ½H₂, E° = 0

E = E° − (0.0591/1) log(1/[H⁺])

E = 0 − 0.0591 × pH (because −log[H⁺] = pH)

E = −0.0591 × 10 = −0.591 V

NCERT 2.18
Predict the products of electrolysis of aqueous CuCl₂ with platinum electrodes.
Show Solution

Solution:

At cathode: Possible reductions — Cu²⁺ → Cu (E° = +0.34) vs 2H₂O → H₂ (E° = −0.83). Cu²⁺ wins (higher E°). Deposit of copper at cathode.

At anode: Possible oxidations — 2Cl⁻ → Cl₂ (E° = +1.36) vs 2H₂O → O₂ (E° = +1.23). Oxygen has lower oxidation potential, but overpotential of Cl₂ is low, so Cl₂ is actually produced preferentially in concentrated solution. In dilute solution, O₂ may form.

Products: Cu at cathode + Cl₂ at anode (with concentrated CuCl₂)

NCERT 2.20
What is a fuel cell? Explain the working of H₂-O₂ fuel cell.
Show Solution

Fuel cell: A galvanic device that converts chemical energy of a continuously supplied fuel into electricity. Unlike batteries, it doesn't run down as long as fuel is supplied.

H₂-O₂ fuel cell:

Anode: 2H₂ + 4OH⁻ → 4H₂O + 4e⁻

Cathode: O₂ + 2H₂O + 4e⁻ → 4OH⁻

Overall: 2H₂ + O₂ → 2H₂O

Efficiency: ~70% (much higher than heat engines at 30-40%)

Byproduct: Only water (pollution-free)

Applications: Spacecraft (Apollo, Gemini, Space Shuttle — provide both electricity and drinking water), electric vehicles (Toyota Mirai, Honda Clarity)

NCERT 2.21
Explain why rusting of iron is an electrochemical phenomenon.
Show Solution

Solution: Rusting occurs via electrochemical mechanism:

Anode (small area): Fe(s) → Fe²⁺(aq) + 2e⁻

Cathode (larger area, in presence of O₂ + moisture): O₂ + 4H⁺ + 4e⁻ → 2H₂O (acidic) OR O₂ + 2H₂O + 4e⁻ → 4OH⁻ (neutral)

Further oxidation: Fe²⁺ + ½O₂ + H₂O → Fe(OH)₂ → Fe(OH)₃ → Fe₂O₃·xH₂O (rust)

Rust is hydrated iron(III) oxide. Requires both oxygen and moisture. Salt accelerates rusting by making the solution more conducting. This mechanism is why zinc (more reactive) can protect iron — galvanization!

NCERT 2.30
The electrical resistance of a column of 0.05 M NaOH solution of diameter 1 cm and length 50 cm is 5.55 × 10³ ohm. Calculate its resistivity, conductivity and molar conductivity.
Show Solution

Solution: Area A = πr² = π(0.5)² = 0.785 cm²

Resistivity: ρ = R × A/l = 5.55×10³ × 0.785 / 50 = 87.1 Ω·cm

Conductivity: κ = 1/ρ = 1/87.1 = 0.01148 S/cm

Molar conductivity: Λ_m = κ × 1000 / M = 0.01148 × 1000 / 0.05 = 229.6 S·cm²/mol

Quick Reference

📐 Complete Formula Sheet

Chapter 2 — All Formulas on One Page

Cell EMF
E°_cell = E°_cathode − E°_anode
Nernst Equation
E = E° − (0.0591/n) log Q
Nernst (General)
E = E° − (RT/nF) ln Q
Gibbs Energy
ΔG = −nFE
Standard Gibbs
ΔG° = −nFE°_cell
Equilibrium Constant
E°_cell = (0.0591/n) log K
Conductance
G = 1/R (S)
Conductivity
κ = (1/R) × (l/A)
Molar Conductivity
Λ_m = κ × 1000 / M
Kohlrausch's Law
Λ°_m = ν₊λ°₊ + ν₋λ°₋
Degree of Dissociation
α = Λ_m / Λ°_m
Dissociation Constant
K_a = Cα² / (1−α)
Solubility (from κ)
s = κ × 1000 / Λ°_m
Faraday's 1st Law
m = MIt / (nF) = QM/(nF)
Faraday's 2nd Law
m₁/m₂ = (M₁/n₁)/(M₂/n₂)
Charge
Q = I × t (Coulombs)
Faraday Constant
F = 96,485 C/mol
Kohlrausch (Weak)
Λ°(CH₃COOH) = Λ°(CH₃COONa)+Λ°(HCl)−Λ°(NaCl)

Important Constants and Standard Potentials

Faraday constant F 96,485 C/mol Charge of 1 mol electrons
R (gas constant) 8.314 J/(mol·K) or 0.0821 L·atm/(mol·K)
1 F 1 mol e⁻ Deposits 1 mol monovalent ions
E°(Li⁺/Li) −3.04 V Most negative (strongest reducing)
E°(Zn²⁺/Zn) −0.76 V Anode in Daniell cell
E°(Fe²⁺/Fe) −0.44 V Rusting anode
E°(H⁺/H₂) 0.00 V SHE reference
E°(Cu²⁺/Cu) +0.34 V Cathode in Daniell cell
E°(Ag⁺/Ag) +0.80 V Common reference electrode
E°(Au³⁺/Au) +1.50 V Very positive (noble metal)
2.303 RT/F at 298 K 0.0591 V Nernst constant
1 S 1 Ω⁻¹ Siemens (conductance unit)

📖 Notation Key

E, E° Cell potential, standard cell potential
E°_cell E°_cathode − E°_anode
n Number of electrons transferred
F Faraday constant (96,485 C/mol)
Q Reaction quotient
K Equilibrium constant
ΔG Gibbs free energy change
R Gas constant
G Conductance (S or Ω⁻¹)
κ Conductivity (S/cm)
Λ_m Molar conductivity (S·cm²/mol)
Λ°_m Limiting molar conductivity
λ° Limiting ionic molar conductivity
α Degree of dissociation
m Mass deposited (g)
I Current (A)
t Time (s)
Z Electrochemical equivalent (g/C)
One-Page Revision

📌 Chapter Summary

Everything You Need to Remember

  1. Galvanic cell: Spontaneous redox → electricity. Anode = oxidation (negative terminal), cathode = reduction (positive terminal).
  2. Cell notation: Anode | Anode solution || Cathode solution | Cathode
  3. E°_cell = E°_cathode − E°_anode. Positive E° → spontaneous reaction. Standard state: 1 M, 1 bar, 298 K.
  4. SHE (Standard Hydrogen Electrode): Pt | H₂ (1 bar) | H⁺ (1 M), assigned E° = 0.00 V.
  5. Nernst equation: E = E° − (0.0591/n) log Q at 298 K. Q = products/reactants.
  6. ΔG = −nFE. ΔG° = −nFE°_cell. Spontaneous when ΔG < 0 (E > 0).
  7. Equilibrium: E°_cell = (0.0591/n) log K. At equilibrium E = 0.
  8. Conductivity κ = G(l/A). Molar conductivity Λ_m = 1000κ/M. Λ_m ↑ with dilution; κ ↑ with concentration.
  9. Kohlrausch's law: Λ°_m = sum of independent ion contributions. Enables calculation of Λ°_m for weak electrolytes.
  10. Degree of dissociation: α = Λ_m/Λ°_m. K_a = Cα²/(1−α).
  11. Faraday's 1st law: m = MIt/nF. 2nd law: masses ∝ equivalent weights.
  12. 1 Faraday = 96,485 C = charge on 1 mol electrons.
  13. Batteries: Primary (dry cell, mercury — irreversible), Secondary (lead-acid, Ni-Cd, Li-ion — reversible), Fuel cells (H₂-O₂ — continuous fuel supply).
  14. Corrosion: Electrochemical degradation. Rusting of Fe = anode Fe → Fe²⁺, cathode O₂ reduction. Prevention: galvanization, cathodic protection, painting, alloying.
  15. Common E° values: Li −3.04, Zn −0.76, Fe −0.44, H 0.00, Cu +0.34, Ag +0.80, Au +1.50.
Exam Preparation

🎯 Common Exam Questions

2-Mark Questions

  1. Define the terms: anode, cathode, and cell potential. Which is oxidation and which is reduction?
  2. Why is SHE used as a reference electrode? What is its assigned potential?
  3. State Faraday's two laws of electrolysis.
  4. What is the significance of salt bridge in a galvanic cell?
  5. How does molar conductivity vary with dilution for strong and weak electrolytes?
  6. Define the terms primary and secondary batteries with examples.

3-Mark Questions

  1. Calculate the EMF of the following cell at 298 K: Al | Al³⁺ (0.01 M) || Fe²⁺ (0.1 M) | Fe. Given E°(Al³⁺/Al) = −1.66 V, E°(Fe²⁺/Fe) = −0.44 V.
  2. Explain why the EMF of a galvanic cell is reduced as the reaction proceeds.
  3. Calculate the mass of silver deposited when 5 A current is passed for 1 hour through AgNO₃ solution. (M_Ag = 108, n = 1)
  4. Explain why galvanized iron is more resistant to corrosion than ordinary iron.
  5. State Kohlrausch's law. How can it be used to calculate the molar conductivity of a weak electrolyte?
  6. Why is Li-ion battery preferred over lead-acid battery for electric vehicles?

5-Mark Questions

  1. Derive the Nernst equation for a general cell reaction. Explain the significance of each term.
  2. Define molar conductivity and conductivity. Derive the relationship Λ_m = 1000κ/M.
  3. Describe the working of a H₂-O₂ fuel cell. What are its advantages over conventional power sources?
  4. Explain the electrochemical mechanism of rusting of iron. What are the methods of preventing it?
  5. Calculate ΔG° and K for the reaction: 2Ag⁺ + Cu → Cu²⁺ + 2Ag. E°_cell = 0.46 V. Is the reaction spontaneous?
  6. A solution of CuSO₄ is electrolyzed for 10 min with a current of 1.5 A. What is the mass of Cu deposited? What volume of O₂ at STP would be produced at anode?

Numericals to Practice

  1. Calculate the EMF of the Daniell cell when [Zn²⁺] = 0.01 M and [Cu²⁺] = 0.1 M at 298 K. (E° = 1.10 V)
  2. The conductivity of 0.01 M KCl solution is 1.4 × 10⁻³ S/cm. Calculate its molar conductivity.
  3. Λ°_m(NaCl) = 126.4, Λ°_m(HCl) = 426.2, Λ°_m(CH₃COONa) = 91.0. Calculate Λ°_m for acetic acid.
  4. Calculate the standard EMF of a cell with Zn/Zn²⁺ and Ag⁺/Ag electrodes. (E° Zn = −0.76 V, E° Ag = +0.80 V)
  5. How long must a current of 2 A pass through AgNO₃ solution to deposit 5 g Ag? (M = 108, n = 1)
  6. The solubility of AgCl is 1.06 × 10⁻⁵ M. Given Λ°_m(AgCl) = 138.3 S·cm²/mol, calculate its conductivity in saturated solution.
Test Yourself

✍️ MCQ Practice

Score: 0 / 18
New Pattern

🎯 Assertion–Reason

(A) Both true, R explains A. (B) Both true, R does NOT explain A. (C) A true, R false. (D) A false, R true.

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Quick Revision

⚡ Formula Flashcards

The formula is shown on every card for quick revision before exams.

Nernst Equation
E = E° − (0.0591/n) log Q
Gibbs & EMF
ΔG = −nFE
Equilibrium Constant
E°_cell = (0.0591/n) log K
Molar Conductivity
Λ_m = κ × 1000 / M
Conductivity
κ = G × (l/A) = (1/R)(l/A)
Degree of Dissociation
α = Λ_m / Λ°_m
K_a (weak acid)
K_a = Cα² / (1−α)
Faraday's 1st Law
m = MIt / (nF)
Faraday's 2nd Law
m₁/m₂ = (M₁/n₁)/(M₂/n₂)
Faraday Constant
F = 96,485 C/mol
Cell EMF
E°_cell = E°_cathode − E°_anode
Kohlrausch's Law
Λ°_m = ν₊λ°₊ + ν₋λ°₋